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Occurrence and Production of Niobium
Occurrence
The element is never found as a free element but does occur in the minerals columbite ((Fe,Mn)(Nb,Ta)2O6), columbite-tantalite or coltan ((Fe,Mn)(Ta,Nb)2O6), pyrochlore ((Na,Ca)2Nb2O6OH,F), and euxenite ((Y,Ca,Ce,U,Th)(Nb,Ta,Ti)2O6). Minerals that contain niobium often also contain tantalum. Large deposits of niobium have been found associated with carbonatites (carbon-silicate igneous rocks) and as a constituent of pyrochlore. Brazil and Canada are the major producers of niobium mineral concentrates and extensive ore reserves are also in Nigeria, Democratic Republic of Congo, and in Russia. A large producer in Brazil is CBMM located in Araxa, Minas Gerais.